岩浆分离结晶作用的微量元素广义初始比值计算方法     

沙连哲 《岩石学报》1991,7(1):26-35

本文提出了一种如何从分异的派生岩浆追溯和反演演化前的原生岩浆的微量元素初始比值的方法。据分离结晶方程logaC_1~q=k·loga C_1~p b,得广义初始比值:C_0~q/(C_0~p)~k=a~b。它与已公认的原生岩浆的判别参数如~(87)Sr/~(86)初始比、δ~(18)O‰、SI、Mg′值及微量元素丰度等有极好的一致性。并将这种方法应用于两个实例,得出大宁花岗闪长岩及其暗色微粒包体分属壳源和幔源;五大连池富钾火山岩的原生岩浆为白榴苦橄碧玄岩浆,而其中的超镁铁质岩包体则是分离结晶的火成堆晶体。  相似文献   

西南极菲尔德斯半岛第三纪钙碱性火山岩的生成与演化     

郑祥身  刘小汉 《岩石学报》1991,7(2):28-37

西南极菲尔德斯半岛第三纪火山岩的岩石学和岩石化学特征表明,它们基本属于钙碱性火山岩系列,是岛弧火山作用的产物。该岩石组合中,随岩石中SiO_2含量的增加,斜长石斑晶数量减少,微量元素Cr、V丰度降低,Sr、Ba丰度下降,这些揭示了岩浆中斜长石和单斜辉石的分离结晶作用。稀土元素的系统变化也证明了这一点。主元素和微量元素的定量计算所验证了岩浆的分离结晶作用演化过程。  相似文献   

北京四合堂花岗质杂岩的两种演化趋势     

Liu Shuwen 《吉林大学学报(地球科学版)》1990,(2)

北京密怀隆起西部的石城片麻岩、皂树片麻岩和云蒙山北部的片麻状花岗闪长岩是太古代同源岩浆演化形成的古深成侵入体,本文称之为四合堂花岗质杂岩。该杂岩中的石城片麻岩,皂树片麻岩的闪长质、石英门长质片麻岩—英云间长质片麻—脉状的奥长花岗岩构成了英云间长岩—奥长花岗岩演化趋势,片麻岩中的石英闪长质片麻岩与花岗间长岩—二长花岗岩构成了钙碱性演化趋势。这两个演化趋势是在不同的条件下分离的矿物相不同所致。  相似文献   

Crystallization of microlites during magma ascent: the fluid mechanics of 1980–1986 eruptions at Mount St Helens     

C.-H. Geschwind  M. J. Rutherford 《Bulletin of Volcanology》1995,57(5):356-370

Eruptions of Mount St Helens (Washington, USA) decreased in intensity and explosivity after the main May 18, 1980 eruption. As the post-May 18 eruptions progressed, albitic plagioclase microlites began to appear in the matrix glass, although the bulk composition of erupted products, the phenocryst compositions and magmatic temperatures remained fairly constant. Equilibrium experiments on a Mount St Helens white pumice show that at 160 MPa water pressure and 900°C, conditions deduced for the 8 km deep magma storage zone, the stable plagioclase is An₄₇. The microlites in the natural samples, which are more albitic, had to grow at lower water pressures during ascent. Isothermal decompression experiments reported here demonstrate that a decrease in water pressure from 160 to 2 MPa over four to eight days is capable of producing the albitic groundmass plagioclase and evolved melt compositions observed in post-May 18 1980 dacites. Because groundmass crystallization occurs over a period of days during and after decreases in pressure, microlite crystallization in the Mount St Helens dacites must have occurred during the ascent of each magma batch from a deep reservoir rather than continuously in a shallow holding chamber. This is consistent with data on the kinetics of amphibole breakdown, which require that a significant portion of magma vented in each eruption ascended from a depth of at least 6.5 km (160 MPa water pressure) in a matter of days. The size and shape of the microlite population have not been studied because of the small size of the experimental samples; it is possible that the texture continues to mature long after chemical equilibrium is approached. As the temperature, composition, crystal content and water content of magma in the deep reservoir remained approximately constant from May 1980 to at least March 1982, the spectacular decrease in eruption intensity during this period cannot be attributed to changes in viscosity or density of the magma. Simple fluld mechanical considerations indicate, however, that the observed changes in mass flux of magma can be modelled by a five-fold decrease in conduit radius from 35 to 7 m, produced perhaps by plating of magma along the conduit walls. The decreased ascent rates which accompanied the decrease in conduit radius can explain the change from closed-system to open-system degassing and the shift from explosive to effusive eruptions during 1980.  相似文献   

CaCO₃生物矿化的研究进展——有机质的控制作用   总被引：9，自引：0，他引：9  

张刚生  谢先德 《地球科学进展》2000,15(2):204-209

生物CaCO₃是自然界分布最广泛的一类生物矿物,其组成除了无机相的CaCO₃外,还含有少量的有机质,包括水可溶(SM)和水不可溶有机质(IM),SM富含阴离子基团,是控制CaCO₃结晶的重要因素之一。通过有机—无机界面分子识别,有机质选择性地与CaCO₃晶体特定方向的面网相互作用,从而对CaCO₃的生长、形貌、多型及结晶学定向等产生明显的控制作用。有机—无机界面的分子识别机制包括静电、晶格几何匹配和立体化学互补等。仿生矿化的研究为进一步深入了解生物矿化的机理及制造高级复合材料提供了新的方法。  相似文献   

富闪深成岩的成因及其地球动力学意义   总被引：1，自引：0，他引：1  

袁玲玲  张晓晖  翟明国  薛富红 《岩石学报》2016,32(5):1556-1570

富闪深成岩是一套以角闪石为标志矿物的侵入杂岩,可由角闪石岩、角闪辉长岩、角闪闪长岩、(英云)闪长岩、黑云母花岗岩等不同酸度系列的岩石组成。在元素地球化学方面,富闪深成岩可呈低钾拉斑质、钙碱性或钾玄质,富集大离子亲石元素和轻稀土元素。起源于经俯冲作用改造的岩石圈地幔或软流圈地幔部分熔融的基性母岩浆通过分离结晶、同化-混染,或与壳源岩浆混合,形成富闪深成岩系列中不同的岩性端元。高水含量作为富闪岩浆体系的基本特征不仅塑造了杂岩体的标志性角闪石矿物学特征,也主导了岩浆的钙碱性演化趋势。富闪杂岩形成环境相对特殊,通常产于板块会聚终末期的洋脊-海沟交互场景和后碰撞阶段,并受到同时期区域构造作用控制。基于野外产出上的共生性和地球化学的相似性,富闪深成岩与高Ba-Sr花岗岩、晚太古代赞岐岩类存在密切的成因关联,对其进行类比研究,不仅有助于富闪深成岩成因解析,也可为探讨大陆地壳生长-分异机制及地球早期构造体制提供崭新视角。最后,作为显生宙克拉通早期破坏过程的重要岩浆记录,华北克拉通北缘发育的多期晚古生代富闪深成杂岩有望为揭开富闪深成岩成因和地球动力学奥秘提供重要的野外实验室。  相似文献   

利用元素分析仪测定锰结核中化合水     

汪依凡  黄德佩  崔淑英 《海洋科学》1990,14(4):48-52

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Simultaneous operation of opposing reaction mechanisms: The influence of matrix heterogeneity on post-kinematic garnet crystallization in an inverted metamorphic sequence     

Freya R. George  Fred Gaidies 《Journal of Metamorphic Geology》2020,38(7):743-769

Metapelites from the inverted Barrovian sequence in the Sikkim Himalaya (northeast India) are shown to be largely continuous with respect to their bulk rock compositions, microstructures and pressure–temperature–time–deformation (P–T–t–D) histories. However, the upper garnet–lower staurolite zone demarcates a region of microstructurally anomalous post-kinematic garnet populations contained within strongly segregated matrices. The different microstructures within samples from this region cannot be attributed to differences in their thermobarometric histories or bulk compositions, but are instead interpreted to represent an otherwise unexposed level of the Daling Group that is now exposed along a post-metamorphic thrust splay. These heterogeneous samples contain several discrete garnet populations that progressively crystallized with increasing P–T. Garnet populations that experienced the most protracted growth now form complex polycrystals that exhibit crystallographically controlled and morphologically irregular interfaces adjacent to micaceous and quartzofeldspathic domains respectively. Electron backscatter diffraction indicates that these polycrystalline garnet structures contain numerous coalesced porphyroblasts that are structurally uncorrelated across their grain boundaries. However, a crystallographically preferred orientation at the polycrystal scale is interpreted to derive from epitaxial crystallization of early-formed garnet porphyroblasts on precursor mica. Later-nucleated porphyroblasts within polycrystals preferentially concentrated towards quartzofeldspathic domains, with the overall nucleation distribution likely controlled by a complex interplay between chemical heterogeneities, strain partitioning and epitaxial crystallization. The subsequent growth of these polycrystals was equally spatially heterogeneous; it was moderated by differences in the efficiency of grain boundary transfer between quartzofeldspathic and micaceous domains that precluded thin section-scale chemical equilibration. In contrast to samples from Sikkim containing more typical porphyroblastic populations in continuous and disseminated matrices, heterogeneous availability of garnet-forming components within this strongly layered matrix is shown to have resulted in grain-scale variations in growth rates and the spatial juxtapositioning of interface-controlled microstructures and locally equilibrated chemical compositions with those that were transport controlled.  相似文献   

冻结过程中单孔冰结晶变形机制研究     

张永安  应赛  文桃  王月礼  周自强  卢千禧  张支立 《冰川冻土》2022,44(5):1429-1439

孔隙水在冻结过程中产生的冰结晶压力导致了多孔材料的冻胀及破坏。本文通过理论分析分别给出了不同形状晶体的结晶压力计算模型,并分析了经典结晶压力计算公式的使用条件。建立了降温过程中孔隙冰晶生长模型,实现冰晶生长过程中的孔隙变形计算,分析了晶核密度、孔径大小、荷载和冰晶体积对孔隙冻胀变形的影响机制。结果表明：起始孔隙直径和长宽比的增大对结晶变形抑制作用的机理在于减少了冰晶体积中膨胀结晶的比例。荷载对孔隙变形的抑制机制在于,荷载的增大迫使冰晶更多地横向生长（长宽比增大）,导致膨胀结晶所占比例减小。孔隙中的晶体生长有完全填充模式和部分填充模式,在部分填充模式下,晶核密度、荷载和孔径的增大都会导致晶体在孔隙中的填充率增大,从而对孔隙结晶变形产生影响。本模型揭示了单个孔隙中冻胀变形机制,为解决多孔介质的冻胀变形与破坏问题提供了新的思路。  相似文献   

内生碳酸岩型稀土矿床中磷酸盐作用研究综述     

许丹妮  宋文磊  杨金昆  陈倩  刘涛涛  徐亦桐 《地质论评》2023,69(6):2023060015-2023060015

碳酸岩型稀土矿床是全球稀土最主要的来源。磷酸盐是该成矿体系中常见的组分,但对其在碳酸岩稀土成矿过程中的具体作用仍缺少系统的认识。本文综述了磷酸盐在碳酸岩岩浆形成、演化和稀土富集成矿过程中作用,并提出现存问题和研究展望。磷在碳酸盐熔体中具有很高的溶解度。磷的存在有利于稀土在地幔极低程度部分熔融过程和碳酸盐—硅酸盐液态不混溶过程中优先进入碳酸盐熔体,形成初始碳酸岩熔体中稀土的预富集。碳酸岩岩浆演化过程中,稀土将优先进入到不混溶的磷酸盐熔体或独居石和磷灰石等磷酸盐矿物中,这些熔体和矿物的行为很可能是控制体系中稀土行为和成矿潜力的关键因素。岩浆作用过程中形成的富稀土磷酸盐矿物还可为热液阶段稀土矿化提供成矿物质来源。磷酸盐还是热液过程中稀土的有效沉淀剂,有利于轻重稀土矿物在流体晚期阶段成矿。未来工作应更多关注磷酸盐在碳酸岩岩浆演化过程中的作用及其中重稀土的富集机理研究,针对具体成岩成矿过程开展实验岩石学和熔体包裹体研究。  相似文献